The minimum pressure required to compress 600 dm3 of a gas at 1 bar to 150 dm3 at 40°C is

  •  4.0 bar

  •  0.2 bar

  •  1.0 bar

  •  2.5 bar

A certain gas takes three times as long to effuse out as helium. Its molecular mass will be:

  •   36 u

  •   64 u
  •   9 u
  •   27 u

A bubble of air is underwater at a temperature15°C and the pressure 1.5 bar. If the bubble rises to the surface where the temperature is 25°C and the pressure is 1.0 bar, what will happen to the volume of the bubble?

  • Volume will become greater by a factor of 2.5

  • Volume will become greater by a factor of 1.6
  • Volume will become greater by a factor of 1.1
  • Volume will become smaller by a factor of 0.70

The pressure exerted by 6.0 g of methane gas in a 0.03 m3 vessel at 129 ºC is
(Atomic masses : C = 12.01, H = 1.01 and R = 8.314 JK–1mol–1)

  • 13409 Pa

  • 41648 Pa

  • 31684 Pa

  • 215216 Pa

For real gases van der Waals equation is written as

(P+an2V2) (V-nb) = nRT

Where 'a' and 'b' are van der Waals constants.


Two sets of gases are :
(I) O2, CO2 , H2 and He        (II)CH4, O2  and H2 
The gases given in set-I in increasing order of 'b' and gases given in set-II in decreasing order of 'a', are arranged below. Select the correct order from the following :

  •  ( I)O2<He<H2<CO2(II) H2>O2>CH4

  •  ( I)H2<He<O2<CO2(II) CH4>O2>H2

  •  ( I)H2<O2<He<CO2(II) O2>CH4>H2

  •  ( I)He<H2<CO2<  O2(II) CH4>H2>O2

Average molar kinetic energy of CO and N2 at same temperature is :

  • KE1 = KE2

  •  KE1 > KE2

  •  KE1 < KE2

  • Can't say anything. Both volumes are not given

In a gaseous mixture which of NO2 , CO2 , and N2O gases have same rate of diffusion :

  •  NO2 , CO2

  •  CO2 , N2O

  •  NO2 , N2O

  • All of the above.

If 400 ml gas at 500 torrs and 666.6 ml gas at 600 torrs is taken in a container of 3 liters, the total pressure of the mixture is

  •   200 torr

  •   400 torr

  •   600 torr

  •   50 torr

The temperature of 4.0 mole of a gas occupying 5 dm3 at 3.32 bar is -
(R = 0.083 bar dm
3 K–1 mol–1).

  • 40 K 

  • 30 K 

  • 20 K

  • 50 K 

The volume occupied by 8.8 g of CO2 at 31.1°C and 1 bar pressure is -
(R = 0.083 bar L K
–1 mol–1)

  • 4.05 L 

  • 3.05 L 

  • 6.05 L 

  • 5.05 L 

 As per Charles's law ,–273° C is the lowest possible temperature because-

  • All gases get liquefied before reaching a temperature of – 273° C.

  • All gases get liquefied after reaching a temperature of – 273° C.

  • All gases have a critical temperature of –273° C.

  • None of the Above.

The correct relation between density (ρ) and pressure of gas (P) is-

  •  P α d2

  •  P α 1d

  •  P α d

  • None of the above

A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. The pressure would be-

  • 0.6 bar

  • 1.2 bar

  • 0.8 bar

  • 0.4 bar

The plots of different values of pressure versus temperature are shown in the given figure. The correct order of volume for the following plot is-

     

  • V4 < V3 < V2 < V1

  • V4 > V3 < V2 > V1

  • V4 > V3 > V2 > V1

  • V4 > V3 > V2 < V1

Pressure versus volume graph for a real gas and an ideal gas is shown below: 

  

The correct statement among the following is -

  • Real gases show a large deviation from ideal behaviour at low pressure.

  • Real gases show a very small deviation from ideal behaviour at low pressure.

  • Real gases do not behave ideally under any conditions at low pressure.

  • None of the above statements is correct

Consider the following graph:

  

The curve that represents CO2 gas is - 

  • X

  • Y

  • Both X and Y 

  • Cannot predict from the graph

The variation of pressure with the volume of the gas at different temperatures can be
graphically represented as per the following graph:

  

If the temperature increases from 200K to 400K (at constant pressure), the volume of a
gas would-  

  • Increase

  • Decrease

  • Remain constant

  • 1st decreases then increases

A plot of pressure versus 1V for a gas at constant temperature is given below:

The relation between  T1, T2, and T3 is- 

 1. T1>T2>T32. T1<T2<T33. T1>T2<T34. None of the above

  • 1
  • 2
  • 3
  • 4

Choose the correct option for graphical representation of Boyle's law, which shows a graph of pressure vs. volume of a gas at different temperatures :

  •  

  •  

  •  

  •  

[Given R=0.082 L atm mol-1 K-1, T=273 K]

Choose the correct option for the total pressure (in atm) in a mixture of 4 g O2 and 2 g H2 confined in a total volume of one litre at 0°C is :

  • 25.18

  • 26.02

  • 2.602

  • 2.518

A neon-dioxygen mixture contains 70.6 g dioxygen and 167.5 g neon. If the pressure of the mixture of gases in the cylinder is 25 bar. The partial pressure of dioxygen and neon in the mixture are respectively-

  • 5.25 bar; 19.75 bar

  • 19.75 bar; 5.25 bar

  • 4.75 bar; 4.75 bar

  • 10.34 bar; 20.25 bar

Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the gas particles. Critical temperatures of ammonia and carbon dioxide are 405.5 K and 304.10 K respectively. The gas liquify first when cooling start from 500 K to their critical temperature, is-

  • Ammonia

  • Carbon dioxide

  • Both liquify at same time

  • Cannot predict

A vessel contains 1.6 g of dioxygen at STP (273.15K, 1 atm pressure). The gas is now transferred to another vessel at constant temperature, where pressure becomes half of the original pressure.
The volume of the new vessel is -
 
  • 1.12 litre
  • 2.24 mL
  • 2.24 litre
  • 1.12 mL

Two different gases 'A' and 'B' are filled in separate containers of equal capacity under the same conditions of temperature and pressure. On increasing the pressure slightly, the gas 'A' liquifies but gas 'B' does not liquefy even on applying high pressure until it is cooled. Incorrect statement among the following regarding above observation is -

  • The behaviour of two gases at increasing pressure is different means they have different critical temperature.
  • 'A' is having lesser force of attraction among the molecules than 'B'
  • "A" gas has low critical temperature that's why on applying pressure it is liquified.
  •  "B" gas has high critical temperature so "B" needs to cool even on application of pressure.

One of the assumptions of kinetic theory of gases states that “there is no force of attraction between the molecules of a gas.”  The incorrect statement among the following regarding the above postulate is-


 

  • This is valid for an ideal gas only.
  • The real gas can be liquefied.
  • 3. This is valid for both ideal and real gases.
  • 4. An ideal gas cannot be liquefied.
For real gases, the effect on value of Z above Boyle’s temperature is-
  •  Above Boyle's temperature, real gases show positive deviation.
  •  Above Boyle's temperature, real gases show negative deviation.
  •  Above Boyle's temperature, real gases show  zero deviation.
  • Above Boyle's temperature, ideal gases show positive deviation.

The correct sequence of increasing order of viscosity among the following is -

  • Hexane < Water = Glycerine
  • Hexane > Water < Glycerine
  • Hexane < Water > Glycerine
  • Hexane < Water < Glycerine

Laminar flow indicates-
a. The velocity of molecules is not same in all the layers.
b. The velocity of molecules is  same in all the layers.
c. Type of flow in which there is a regular gradation of velocity on passing from one layer to the next.
d. The velocity of the upper layers increases as the distance of layers from the fixed layer increases.
  •   b,c,d
  •   a,c,d
  •   b,c
  •   a,b,c
0:0:1


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