The number of d- electrons retained in Fe2+ :

  • 5

  • 6

  • 3  

  • 4

Which of the following sets of quantum numbers is not possible?

  • n = 1, l=0, m=0, s=1/2

  •  n = 2, l=0, m=0, s= -1/2

  •  n = 3, l= 3, m = -3, s = 1/2

  •  n = 3, l= 1, m = 0, s = -1/2

Which of the following sets of quantum numbers represent an impossible arrangement - 

       n   l    m     s

  •     3   2   -2    (+)1/2

  •     4   0   0     (-)1/2

  •     3   2   -3    (+)1/2

  •     5   3   0     (-)1/2

How many unpaired electrons are present in Ni2+ cation (atomic number = 28)

  • 0

  • 2

  • 4

  • 6

Number of unpaired electrons in 1s2 2s2 2p3 is -

  • 2

  • 0

  • 3

  • 1

The quantum numbers of four electrons are given below.

                                  n            l           m          s 

(1) Electron 1             3            0             0           -1/2

(2) Electron 2             4            0             0           1/2

(3) Electron 3            3             2             0           1/2

The correct order of decreasing energy of these electrons is - 

1. Electron 3 > Electron 1 > Electron 4> Electron 2

  • 3. Electron 3 > Electron 2 > Electron 4 > Electron 1

  • 4. Electron 2 > Electron 4 > Electron 3 > Electron 1

  • 2. Electron 4> Electron 2 > Electron 3 > Electron 1

  • (4) Electron 4            3             1             0           -1/2

Which type of radiation is not emitted by the electronic structure of atoms:

  • y-rays

  • Ultraviolet light

  • X-rays

  • Visible light

An absorption line of the lowest frequency in the transition of hydrogen spectra is

  • n=3 to n=8

  • n=1 to n=2

  • n=2 to n=1

  • n=8 to n=3

If uncertainty in the position of an electron is zero the uncertainty in its momentum will be

  • < h/4π

  • > h/4π

  • zero

  • infinite

The maximum number of atomic orbitals associated with a principal quantum number 5 is-

  • 9

  • 12

  • 16

  • 25

The de Broglie wavelength of electron of He+ ion is 3.329Å. If the photon emitted upon de-excitation of this He+ ion is made to hit H atom in its ground state so as to liberate electron from it, what will be the de Broglie's wavelength of photoelectron ?

  • 0.1518 Å

  • 6.1518 Å

  • 2.3518 Å

  • 4.1218 Å

Velocity of helium atom at 300 K is 2.40 x 102 meter per sec. What is its wavelength? (mass number of helium is 4) -

  • 0.416 nm

  • 0.83 nm

  • 803 Å

  • 8000 Å

If the Planck’s constant h=6.6 x 10-34 Js, the de-Broglie wavelength of a particle having the momentum of 3.3 x 10-24 kg m s-1 will be

  • 0.002 Å

  • 0.02 Å

  • 0.2 Å

Which of the following statements is not true with respect to photoelectric effect -

  • The plot of kinetic energy of the photoelectrons against frequency of absorbed radiation gives a straight line parallel to x-axis

  • The plot of K.E. of the photoelectrons against frequency of absorbed radiation gives a straight line with slope equal to h and intercept to work function of metal

  • The plot of kinetic energy of the photoelectrons versus the intensity of incident radiation with constant frequency gives a straight line parallel to x-axis

  • When intensity of light is increased the number of photons ejected increases but the energies of these electrons are the same.

The first line in the Lyman series in the spectrum of hydrogen atom occurs at a wavelength of 1215 Å and the limit for Balmer series is 3645 Å. Calculate the wavelength corresponding to series limit of Lyman series.

  • 911.2 Å

  • 812.2 Å

  • 712.2 Å

  • 678.4 Å

The correct order of increasing energy of atomic orbital is

  • 3s, 3p, 4s, 3d, 4p

  • 3s, 3p, 3d, 4s, 4p

  • 3s, 3p, 4s, 4p, 3d

  • 3s, 3p, 3d, 4p, 4s

In Rutherford's alpha scattering experiment using gold foil, the kinetic energy of the alpha particle was 1.2 x 10-12J. For a head on collision, using the formula K.E. = 14πε0x 2Ze2/r0 , what may be the magnitude of r0 [ The nuclear radius of gold, Z=79; 14πε0= 9 x 109 new-ton/meter2 coulomb-2, e= 1.6x10-19 coulomb]

  • 3 x 10-14m

  • 1.3 x 10-14m

  • 2.1 x 10-14m

  • 4.3 x 10-14m

The quantum number of the most energetic electron in an Ne atom in the first excited state is

  • 2, 1, 0, +1/2

  • 3, 1, 1, +1/2

  • 3, 0, 0, +1/2

  • 3, 1, 0, +1/2

The frequency of line spectrum of sodium is 5.09 x 1014 sec-1. Its wavelength (in nm) will be -[C= 3x108m/sec]

  • 510nm

  • 420nm

  • 589nm

  • 622nm

The total number of neutrons in dipositive zinc ions with mass number 70 is -

  • 34

  • 40

  • 36

  • 38

With a certain exciting radiation of a particular frequency, to which hydrogen atoms are exposed, the maximum number of spectral lines obtainable in the emission is 15. The uppermost energy level to which the electron is excited is 

  • 4

  • 5

  • 6

  • 7

Consider an electron which is brought close to the nucleus of the atom from an infinite distance, the energy of the electron-nucleus system:

  • Increases

  • Decreases

  • Remains the same

  • None of these

When accelerated electrons are direct against an anticathode in an X-ray tube, the radiation obtained has a continuous spectrum with a wavelength minimum,

λmin = (1.24 x 10-6)V) m, where V is the voltage used for accelerating the electrons.

Calculate λmin for V= 5 x 104 volts.

  • 1.25 Å

  • 0.75 Å

  • 0.25 Å

  • 1.00 Å

Calculate the de Broglie wavelength of an α-particle emitted from radium having an energy of 4.8 MeV.

(Mass of α-particle=6.6 x 10-24 g; h=Planck's constant = 6.626 x 10-27 erg sec)

  • 6.18 x 10-13cm

  • 0.58 x 10-8cm

  • 6.58 x 10-13cm

  • 4.12 x 10-11cm

An atom forms an ion by losing three electrons. The ion has an electronic configuration [Ar]3d6. The symbol of the ion is :

  • Fe3+

  • Ni3+

  • Co3+

  • Mn+3

The frequency ratio between violet (400nm) and red (750nm) radiations in the visible spectrum, is-

  • 8/15

  • 4/15

  • 15/8

  • None of these

What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition, n=4 to n=2 in the He+ spectrum?

  • n =4 to n=2

  •   n = 3 to n=2

  •   n =3 to n=1

  •   n =2 to n=1

Using arbitrary energy units we can calculate that 864 arbitrary units (a.u.) are required to transfer an electron in hydrogen atom from the most stable Bohr's orbit to the largest distance from the nucleus 

n =    E= 0

n = 1 ;   E= -864 Arbitrary units

The energy required to transfer the electron from third Bohr's orbit to the orbit n = will be-

  • 96 Arbitrary units

  • 192 Arbitrary units

  • 288 Arbitrary units

  • 384 Arbitrary units

The sub-shell that comes after f-sub-sell is called g-subshell. The number of g-sub orbitals in g-sub-shell and the total number of orbitals in the principal orbital respectively are-

  • 10 and 25

  • 9 and 25

  • 11 and 23

  • 15 and 45

The wavelengths of two photons are 2000 Å and 4000 Å respectively. What is the ratio of their energies?

  • 1/4

  • 4

  • 1/2

  • 2

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