Helium atom can be excited to 1s1, 2p1 configuration by light of 58.44 nm. The lowest excited state with configuration 1s1, 2s1 lies 4857 cm-1 (1/λ) below the 1s1, 2p1 state. What would be the average He - H bond energy so that HeH2 could form, non-endothermically from the lowest excited singlet state of helium? Neglect any difference between G and H and take H as 218 kJ mol-1

  • 1614 kJ mol-1

  • 1212 kJ mol-1

  • 912 kJ mol-1

  • 1511 kJ mol-1

The number of electrons in one molecule of CO2 are - 

  • 22

  • 44

  • 66

  • 88

The ion that is isoelectronic with CO is-

  • CN-

  • O2+

  • O2-

  • N2+

If frequency of the X-rays produced using an element as anti-cathode is found to be 2500 sec-1, the atomic number of used element is (a, b= 1)

  • 51

  • 49

  • 56

  • 72

What is the energy required per mole to excite an electron from the third to fifth Bohr orbit in hydrogen ?

  • 6.336 x 106J

  • 7.122 x 104J

  • 0.343 x 106J

  • 9.343 x 104J

The energy of electron in first Bohr's orbit of H-atom is -13.6 eV. What will be its potential energy in n = 4.

  • –13.6 eV

  • - 3.4 eV

  • -0.85 eV

  • -1.70 eV

Sodium atoms can be ionised by supplying an energy of 118 kcal mol-1. Using this data, calculate the lowest possible frequency of light that can ionise a sodium atom.

(h = 6.624 x 10-27 erg.sec, c= 3 x 1010 cm sec-1).

  • 1.24 x 1015 sec-1

  • 0.24 x 1015 sec-1 

  • 12.4 x 1012 sec-1

  • 2.31 x 1018 sec-1

A glow worm of mass 5.0 g emits red light (650 nm) with a power of 0.1 W. entirely in the backward direction. What velocity would it accelerate to after 10 years, if released in free space (and assumed to be alive)?

  • 9.14 ms-1 

  • 28.08 ms-1

  • 11.05 ms-1

  • 21.04 ms-1

Which of the following postulates does not belong to Bohr's model of the atom?

  • Angular momentum is an integral multiple of h/2π

  • The electron stationed in the orbit is stable

  • The path of an electron is circular

  • The change in the energy levels of electron is continuous

The total number of orbitals having l = 3  is - 

  • 3

  • 7

  • 5

  • 9

Bohr's atomic model can explain:-

  • the spectrum of hydrogen atom only

  • the spectrum of an atom or ion containing one electron only

  • the spectrum of hydrogen molecule

  • the solar spectrum

The presence of one electron each in the three 2p sub-shell of nitrogen is explained by 

  • Uncertainty principle

  • Hund's rule

  • Pauli's principle 

  • Bohr's theory

When the atoms of gold sheet are bombarded with a beam of α -particles, only a few a-particles get deflected where as most of them go straight undeflected. This is because

  • The force of attraction on the α-particles by the oppositely charged electron is not sufficient

  • The nucleus occupies much smaller volume as compared to the volume of atom

  • The force of repulsion on fast moving α-particles is very small.

  • The neutrons in the nucleus do not have any effect on α-particles

Using radiation of wavelength 3500 Å, it is observed that the maximum kinetic energy of the emitted photoelectrons is 1.6 eV for potassium. Calculate the work function of the metal. [h=6.626 x 10-34 Js, 1 eV=1.6 x 10-19 J]

  • 3 eV

  • 2.5 eV

  • 3.5 eV

  • 2 eV

To give designation to an orbital, we need

  • Principal and azimuthal quantum number

  • Principal and magnetic quantum number

  • Azimuthal and magnetic quantum number

  • Principal, azimuthal and magnetic quantum numbers.

The rest mass of a proton is 1.673 x 10-27 kg and that of the electron is 9.109 x 10-31 kg. What must be the speed of the proton which has the same de Broglie wavelength as an electron moving with a speed of 9 x 106 m/s?

  • 3600 m/s

  • 4900 m/s

  • 4300 m/s

  • 5600 m/s

Which one of the following statement is not true about the quantum numbers n, l, m and s

  • m gives the information on the energy of the electron in a given orbital.

  • l gives an idea of the shape of the orbital.

  • n gives information on the size of the orbit.

  • s gives the direction of spin of the electron in the orbital.

The number of electrons in the valence shell of calcium is 

  • 6

  • 8

  • 2

  • 4

The brackett series of spectral lines arise when an electron in an excited hydrogen atom jumps from an energy level

  • n=5 to n=1

  • n=5 to n=3

  • n=5 to n=4

  • n=5 to n=2

What is the ratio of the time period of revolution of electron He+ ion sample in the orbit where the path length is three time the de-broglies wavelength to the time period of revolution in the ground state –

  • 27:1

  • 1:27

  • 9:8

  • 8:9

The ratio of the wavelengths of the last lines of the Balmer and Lyman series is-

  • 4:1

  • 27:5

  • 3:1

  • 9:4

The energy of the emitted photon when an electron in Be3+ ion returns from n=2 level to the ground state is 

  • 2.616 x 10-19J

  • 26.16 x 10-17J

  • 261.6 x 10-18J

  • 2616 x 10-17J

The splitting of spectral lines in a magnetic field, arising out of the orbital motion of electrons only and the further splitting due to spin motion are respectively called

  • Zeeman and Stark effects

  • Zeeman and anomalous Zeeman effects

  • Stark and Zeeman effects

  • Zeeman and Kerr effects

A photon of wavelength 300 nm causes the emission of two photons. If the wavelength of one of them is 700 nm. What is the wavelength of the other photon?

  • 525 nm

  • 600 nm

  • 450 nm

  • 300 nm

The electronic transition in the hydrogen atom that emits maximum energy is:

  • 2. 1  4

  • 1. 2&nsp; 1

  • 4. 3  2

  • 3. 4  3

The spectrum of He-atom may be considered similar to the spectrum of - 

  • H

  • Li+

  • Na

  • He+

The Compton wavelength for an electron is  hm0c

calculate λhm0c(1- cos θ) for a scattering angle  θ = π/3. What is the maximum value for λ ?

2. 0.012 Å, 0.048 Å

  • 0.024 Å, 0.048 Å

  • 4. 0.006 Å, 0.012 Å

  • 0.012 Å, 0.024 Å

  • 0.024 Å 

The total spin resulting for a 3d7 configuration is 

  • 3/2

  • 1/2

  • 2

  • 1

Supposing the energy of the fourth shell for the hydrogen atom is -50a.u. (Arbitrary unit). What would be its ionization potential-

  • 50

  • 800

  • 15.4

  • 20.8

An element with atomic mass Z consists of two isotopes of mass number Z-1 and Z + 2. The percentage abundance of the heavier isotope is -

  • 0.25

  • 33.3

  • 66.6

  • 75

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