Two isotopes of Boron are found in the nature with atomic weights 10.01(I) and 11.01(II). The atomic weight of natural Boron is 10.81. The percentage of (I) and (II) isotopes in it are respectively-
20 and 80
10 and 90
15 and 75
30 and 70
Calculate the wavenumber of lines having the frequency of 5 x 1016 cycles per sec.
1.666 x 108m-1
0.666 x 108m-1
4.126 x 106m-1
3.133 x 104m-1
Which of the following set of quantum number is not valid
n = 1 , l = 2
n=2, m = 1
n =3, l = 0
n = 4, l = 2
For particles having same kinetic energy, the de Broglie wavelength is-
Directly proportional to its velocity
Inversely proportional to its velocity
Independent of velocity and mass
Unpredictable
Photochemical dissociation of oxygen results in the production of two oxygen atoms, one in the ground state and one in the excited state.
O2 →hv O→O*
The maximum wavelength () needed for this is 174 nm. If the excitation energy O→O* is 3.15 x 10-19 J. How much energy in kJ mole-1 is needed for the dissociation of one mole of oxygen into normal atoms in ground state?
498.3 kJ mol-1
418.3 kJ mol-1
524.1 kJ mol-1
612.8 kJ mol-1
Rutherford's scattering experiment is related to the size of the-
Nucleus
Atom
Electron
Neutron
The energy needed to convert helium atom to He +2 is -79eV. The first ionization energy of this atom is about
65.4eV
51.8eV
24.6eV
27.2eV
Elements upto atomic number 103 have been synthesized and studied. If a newly discovered element is found to have an atomic number 106, its electronic configuration will be -
[Rn] 5f14, 6d4, 7s2
[Rn] 5f14, 6d1, 7s2 7p3
[Rn] 5f14, 6d, 7s0
[Rn] 5f14, 6d5, 7s1
The most probable radius (in pm) for finding the electron in He+ is -
0
52.9
26.5
105.8
The mass ratio of photons corresponding to the first lines of the Lymann and the Balmer series of the atomic spectrum of hydrogen is :
5:27
1:4
27:5
4:1
An electron, practically at rest, is initially accelerated through a potential difference of 100 volts. It then has a de Broglie wavelength=λ1Å. It then get retarded through 19 volts and then it has wavelength λ2 Å. A further retardation through 32 volts changes the wavelength to λ3.
What is (λ3-λ2)/λ1?
20/41
10/63
20/63
10/41
Which of the following has the maximum number of unpaired electons-
Mg2+
Ti3+
V3+
Fe2+
There are three energy levels in an atom. How many spectral lines are possible in its emission spectra?
One
Two
Three
Four
Azimuthal quantum number defines -
e/m ratio of electron
Spin of electron
Angular momentum of electron
Magnetic momentum of electron
For the energy levels in an atom, which one of the following statements is correct -
There are seven principal electron energy levels
The second principal energy level can have two 'sub energy levels and contains a maximum of eight electrons
The energy level can have a maximum of 32 electrons
4. The 4s sub-energy level is at higher energy than the 3d sub-energy level
Arrange the following particles in increasing order of values of e/m ratio: Electron(e), proton(p), neutron(n) and α-particle(α)
n,p,e,α
n,α,p,e
n,p,α,e
e,p,n,α
The increasing order of energy of electromagnetic radiation can be represented as
microwave < infrared < visible < X-ray
X-ray < visible < infrared < microwave
microwave < infrared < visible < radiowaves
X-ray < infrared < visible < microwave
The wavelength of the photoelectric threshold of metal is 230 nm. Determine the K.E. of photoelectron ejected from the surface by UV radiation emitted from the second-longest wavelength transition (downward) of an electron in Lyman series of the atomic spectrum of hydrogen. (R=1.09677 x 107 m-1)
1.074 x 10-18 J
1.937 x 10-18J
6.213 × 10-18 J
7.123 x 10-10J
Beryllium's fourth electron will have the four quantum numbers :
n l m s
1 0 0 1/2
1 1 1 1/2
2 0 0 -1/2
2 1 0 +1/2
Mass of neutron is ........................times the mass of an electron-
1840
1480
2000
None of the above
If the size of the first orbit of the hydrogen atom is 5.29 nm, the size of the second orbit of He+ is
2.65 nm
21.16 nm
10.58 nm
5.29 nm
Which one of the following is not the characteristic of Planck's quantum theory of radiation –
The energy is not absorbed or emitted in whole number or multiples of quantum
Radiation is associated with energy
Radiation energy is not emitted or absorbed continuously but in the form of small packets called quanta
Magnitude of energy associated with a quantum is proportional to the frequency
3p orbital has -
Two spherical nodes
Two non-spherical nodes
One spherical and one non-spherical node
One spherical and two non-spherical nodes
An isotone of 32Ge76 is:
(i) 32Ge77
(ii) 33As77
(iii) 34Se77
(iv) 34Se78
only (i) & (ii)
only (ii) & (iii)
only (ii) & (iv)
(ii) (iii) & (iv)
Which of the following has greater number of electrons than neutrons?
Al3+
O2-
F-
C
The work function of a metal is 4.2 eV. If radiations of 2000 A0 fall on the metal then the kinetic energy of the fastest photoelectron is
1.6 x 10-19J
16 x 1010J
3.2 x 10-19J
6.4 x 10-10J
The relationship between energy E, of the radiation with a wavelength 8000 A0 and the energy of the radiation with a wavelength 16000 A0 is
E1 = 6E2
E1 = 2E2
E1 = 4E2
E1 = 1/2E2
The transition of electrons in H atom that will emit maximum energy is:
n3 → n2
n4 → n3
n5 → n4
n6 → n5
The transition in the He+ ion in the balmer series that would have the same wave number as the first Lyman line in the hydrogen spectrum is-
2 →1
5 →3
4 →2
6 →4
If the speed of electron in Bohr's first orbit of hydrogen atom be x, then speed of the electron in 3rd orbit is:
x/9
x/3
3x
9x
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