Some Basic Concepts Of Chemistry - Class 11 Medical Chemistry - Extra Questions

Calculate the concentration of NaOH solution in g/mL, which has the same normality as that of a solution of HCl of concentration 0.04 g/mL.



Silver crystallises in fcc lattice. If edge length of the cell is $$4.07\times {10}^{-8}cm$$ and density is $$10.5g$$ $${cm}^{3}$$, calculate the atomic mass of silver.



$$H_2SO_4$$ is 98% by weight of solution, $$M x 10^2$$. What is the value of M?



Insulin contains $$3.4$$% sulpur calculate minimum molecular weight of insulin.



1 atmosphere means how many Pascal?



Which has the highest mass ?
(a) 50 g iron                          (b)  5 moles of $${ N }_{ 2 }$$
(c)  0.1 mol atom of Ag          (d)  $${ 10 }^{ 23 }$$ atoms of carbon



The total mass of reactants and products in a reaction will always be the same. This law is known as:



The atomic mass of carbon is:



16 g of oxygen and 3 g of hydrogen are mixed and kept at 760 mm pressure and 0$$$$. The total volume occupied by the mixture will be nearly
(A) 22.4 litre
(B) 33.6 litres
(C) 448 litres
(D) 44800 ml



What is hydrogen azide?



What are the conditions for something to be called as matter?



Define Avogadro's law. Taking a suitable example prove that it is not in contradiction with Dalton's Atomic Theory.



The percentage of $$3$$ element are as follows in calcium carbonate $$(CaCO_{3})$$ Calcium $$40\%$$, carbon $$12\%$$, Oxygen $$48\%$$. if law of constant proportion is true what weight of these element will be present in $$1.5 g$$ of another sample of calcium carbonates $$(CaCO_{3})$$



An oxide $$M_2O_3$$ contains 10.3 % oxygen by weight. Calculate the atomic weight of M.



A solution contains 50 g of sugar in 350 g of water. Calculate the concentration of solution in terms of mass by mass percent of the solution.



Chlorine occurs in nature in two isotope forms with masses 35u and 37u. The percentage of $$^{35}\textrm{Cl}$$ is 75%. Find the average atomic masses of chlorine atoms. 



Calculate the mass of 0.125 mol NaOH



What is one amu or one 'u'?



Define atomic mass unit.



Define the atomic mass unit.



Calculate the weight of ammonia gas required for reacting with sulphuric acid to give 78 g of fertilizer ammonium sulphate.



$$\text{The following questions are about one mole of sulphuric acid}\ [H_{2}SO_{4}]$$.
find the number of gram hydrogen atoms in 1 mole of $$[H_{2}SO_{4}]$$.



During an experiment the students were asked to prepare a 10% solution of sugar in water. Ramesh dissolved 10g of sugar in 100g of water while Sarika prepared it by dissolving 10g of sugar in water to make 100g of the solution. Compare the mass % of the two solutions.



Give reason: Carbonate and sulphide ores are usually converted into oxides during the process of extraction.



The unified atomic mass unit is the standard unit that is used for indicating mass on an atomic or molecular scale. If true enter 1, else enter 0



Mass and percentage by weight do not change with ________ (temperature/volume).



The solubility of salt at $$30^{\circ}C$$ isCalculate the weight (g) of water required to prepare a saturated solution containing 90 g of salt.



If 11 g of oxalic acid is dissolved in 500 mL of solution (density $$=$$ 1.1 g mL$$^{-1}$$), what is the mass % of oxalic acid in solution?



$$\displaystyle \begin{matrix}Isotope &per\ Natural\ abundance  &Molar\ mass \\^{1}H  &99.985  &1 \\ ^{2}H &0.015  & 2\end{matrix}$$

The average atomic mass of hydrogen using the following data is _________.



The atomic mass of $$_{11}^{23}\textrm{Na}$$ in amu is :



The percent composition by mass of the phosphorus in calcium phosphate $$Ca_3(PO_4)_2$$ is $$x$$. Then, the value of $$x$$ is :



Boron has two stable isotopes, $$^{10}$$B(19%) and $$^{11}$$B(81%). The atomic mass that should appear for boron in the periodic table is ______ .
(Enter the nearest integer value)



The aluminum sulphate hydrate $$[Al_2(SO_4)_3\cdot xH_2O]$$ contains $$8.20$$ percent $$Al$$ by mass. The value of $$x$$, that is, the number of water molecules associated with each $$Al_2(SO_4)_3$$ units is ________. (write the ans in the form of x/3)



Which of the following pairs have equal mass?
(1) $$1$$ amu of $$^{12}\textrm{C}$$ and $$1$$ amu of $$^{13}\textrm{C}$$
(2) $$1$$ mol of $$_{11}^{23}\textrm{Na}$$ and $$1$$ mol of $$_{11}^{24}\textrm{Na}$$
(3) $$0.5$$ mol of $$_{2}^{4}\textrm{He}$$ and $$1$$ mol of $$_{1}^{2}\textrm{H}$$
Answer must be the sequence number of the pair.



$$Al_2(SO_4)_3.xH_2O$$ has $$8.20$$% $$Al$$ by mass. The value of $$x/3$$ is _________. 



Atomic mass unit is also called Dalton(Da). Explain.



Analysis of a metal chloride $$XCl_3$$ shows that it contains $$67.2\%$$ $$Cl$$ by mass. The molar mass of $$X$$ is __________. 



Disilane, $$Si_2H_x$$, is analyzed and found to contain $$90.28\%$$ of silicon by weight, then the value for $$x$$ is $$(Si=28)$$ :



$$Na_2SO_3\cdot yH_2O$$ has $$50\%$$ $$H_2O$$ by mass. Thus, $$y$$ is :



Match $$\%$$ of carbon in List-I with the compound given in List-II.



When $$2.495$$ $$g$$ of $$CuSO_4\cdot xH_2O$$ (molar mass $$249.5$$) is heated, $$0.05$$ mole of $$H_2O$$ is lost. Thus, $$x$$ is:



A solution _______ $$\%$$ by mass of solvent is $$16.67\%$$ by mass of solution. Write the value in the form of $$x\times10$$, where $$x$$ is:



Total number of ions in aluminium phosphate is :



There are_______moles of anion in one mole of sodium sulphate.



If at a particular temperature, the density of $$18\ M \ H_2SO_4$$ is $$1.8$$ g cm$$^{-3}$$. Percentage concentration (%) by mass of solution is :



Matter is neither .......... nor .......... in a chemical reaction.



Calculate the mass percent of $$O$$ present in sodium sulphate $$\displaystyle \left( { Na }_{ 2 }{ SO }_{ 4 } \right)$$.



In diammonium phosphate, $$(NH_4)_2HPO_4$$, the percentage of $$P_2O_5$$ is



Describe law of conservation of matter.



The mass of 94.5 ml of a gas at S.T.P. is found to be 0.2231 g. Calculate its molecular mass.



16 grams of $$NaOH$$ is dissolved in 100 grams of water at 25$$^o$$C to form a saturated solution. Find the solubility and weight percentage of the solution.



Compounds are formed by chemically combining elements in a .................... proportion by weight.



Why do atomic masses of most of the elements in atomic mass units involve fraction?



If $$10 l$$ of oxygen contains x molecules, then $$10 l$$ of ozone contains ______ molecules at the same temperature and pressure.



Calculate the mass of urea $$NH_2CONH_2$$ required in making 2.5 kg of 0.25 molal aqueous solution.



Fill in the blanks with suitable words:
The atomic mass of an atom is $$23$$ and its atomic number is $$11$$. The atom has ________ neutrons.



Fill in the blanks with suitable words.
Average atomic mass of chlorine is ____________.



In the brown ring complex, the oxidation state of iron is:



State Avogadro's law?



a) State any three findings of modem atomic theory.
b) Write down any two applications of Avogadro's law.



Find the concentration of solution in terms of weight percent if $$20$$ grams of common salt is dissolved in $$50$$ grams of water.



Details of some gases taken at $${273}\ K$$ temperature and $$1$$ atm pressure are given in the table.
GasVolume (L)Number of moles
Hydrogen22410
Helium1125
Oxygen22410
Ammonia562.5
(a) On the basis of which gas law, the volume and the number of moles are given in the table?
(b) Represent this gas law in mathematical form.
(c) Among these, if the pressure of hydrogen gas is changed to $$2$$ atm. Calculate the new volume.



Find the concentration of solution in terms of weight percent if $$20g$$ of common salt is dissolved in $$50g$$ of water.



Calculate the weight of lime ($$CaO$$) that can be obtained by heating 200 kg of limestone which is 93% pure. How many moles of impure potassium chlorate of 75% purity is required to produce 48 g of oxygen?



The relative density of a mixture of nitrogen and oxygen is 14.4 (H = 1) and the relative densities of nitrogen and oxygen are 14.0 and 16.0 (H =1)respectively. Calculate the composition of the mixture (i) by volume and (ii) by mass.



2 g mixture of glucose and sucrose is dissolved in 1 litre water at 298 K to develop an osmotic pressure of 0.207 atm. Calculate percentage composition of glucose and sucrose by mole as well as by mass.



Find the amount of zinc in gram necessary to produce $$224ml$$ of $${H}_{2}$$ by the reaction with sulphuric acid.



A 0.24 g sample of compound of oxygen and boron was found by analysis to contain 0.096 g of boron and 0.144 g of oxygen.Calculate the percentage composition of the compound by weight.



Calculate the weight of lime ($$CaO$$) obtained by heating $$200kg$$ of 95% pure lime stone ($$Ca{CO}_{3}$$).

$$Ca{CO}_{3}\rightarrow CaO+{CO}_{2}$$



The density of iron crystal is $$8.54$$ gram $$cm^{-3}$$. If the edge length of unit cell is $$2.8$$ $$A^o$$ and atomic mass is $$56$$ gram $$mol^{-1}$$, find the number of atoms in the unit cell. (Given: Avogadro's number $$=6.022\times 10^{23}$$, $$|A^o=1\times 10^{-8}$$cm).



At 50C, liquid $${ NH }_{ 3 }$$ has ionic product is $${ 10 }^{ -30 }$$. How many amide $$\left( N{ H }_{ { 2 }^{ - } } \right)$$ ions are present per $${ mm }^{ 3 }$$ in pure liquid $${ NH }_{ 3 }$$ ? (take $${ N }_{ A } = 6 \times \ { 10 }^{ 23 }$$)



The self ionisation constant for $$HCOOH$$ is $${10}%{-6}$$ what percentage of $$HCOOH$$ are converted to $$HCOO$$ ion. The density of $$HCOOH$$ is $$1.22g$$ $${mL}^{-1}$$.



Lithium exists in nature in the form of two isotopes, Li-6 and Li-7 with atomic masses 6.0151u and 7.0160u and the percentages 8.24 and 91.76 respectively. Calculate average atomic mass. 



What should be the number of $${{\text{H}}^{\text{ + }}}$$ ions in 1 mL of distilled water, if the number of $${{\text{H}}^{\text{ + }}}$$ ions in  L is $${\text{6}}{\text{.023}} \times {\text{1}}{{\text{0}}^{16}}$$?



State the law of conservation of mass. State the main points of Landolt's experiment for experimental evidence of the law.



Discuss about determining mass percentage of oil from oil seed.



Calculate the percentage loss of mass of hydrated copper[II] sulphate $$[CuSO_4.5H_2O]$$ when it is completely dehydrated. 
$$CuSO_4.5H_2O \to CuSO_4+5H_2O$$
[Atomic weights are $$Cu = 64, S=32, O=16, H=1$$]



92 g mixture of $$CaCO_3$$ and $$MgCO_3$$ heated strongly in an open vessel. After complete decomposition of the carbonates it was found that the weight of residue left behind is 48 g. Find the mass of $$MgCO_3$$ in grams in the mixture.



Calculate the mass per cent of different elements present in sodium sulphate $$(Na_2SO_4)$$.



Claculate the mass % of  different element in $$Na_2SO_4$$ ?



In a Carius determination, $$0.234g$$ of an organic substance gave $$0.334g$$ of barium sulphate. Calculate the percentage of sulphur in the given compound. $$[Ba = 137, S=32, O=16]$$



Calculate the no. of atoms in:
a) 0.5 mol atom of nitrogen
b) 0.2 mol molecules of hydrogen
c)3.2 g of sulphur (Z for sulphur=32)



State and explain law of conservation of mass.



A solution contains 40 grams of common salt dissolved in 345 grams the solution. Calculate the concentration percentage of the solution by mass  percentage.



0.246 g of an organic compound on complete combustion gave 0.198 g of carbondioxide and 0.1014 g of water, then the percentage composition of carbon and hydrogen in the compound respectively
1) 4.58, 21.95           2) 21.95, 4.58
3) 45.8, 2.195          4) 2.195, 45.8



State and explain laws of chemical combination.



If atomic eq. 40% of $$PCl_{ 5 }$$ dissociated. Calculate equivalent molar mass.



Calculate the mass percentage composition of the elements in nitric acid :$$(H=1;N=14,O=16)$$



What is the law of conservation of mass?



Calculate the total number of electrons present in $$18\ mL$$ of water.



Explain the need for a reference atom for atomic mass. Give some information about two reference atoms. 



$$1.20g$$ sample of $${Na}_{2}{CO}_{3}$$ and $${K}_{2}{CO}_{3}$$ was dissolved in water to form $$100ml$$ of a solution. $$20ml$$ of this solution required $$40ml$$ of $$0.1N$$ $$HCl$$ for complete neutralization. Calculate the weight of $${Na}_{2}{CO}_{3}$$ in the mixture.



How much amount of $$CaCO_3$$ in gram having percentage purity 50 per cent produces 0.56 litre of $$CO_2$$ at on heating?



Lithium exists in nature in the form of two isotopes, $$Li-6$$ and $$Li-7$$ with atomic masses $$6.0151u$$ and $$7.0160u$$ and the percentage $$8.24$$ and $$91.76$$ respectively.
Calculate average atomic mass.



Calculate the mass percentage composition of the elements in nitric acid (H = 1, N = 14, O = 16).



Write any two differences between mixture and compound. Also write two examples of each.



The half life of the nuclide $$Rn^{220}$$ is $$54.5$$ sec. Find mass (in kg) of radon is equivalent to $$1$$ millicurie?



Calculate the amount of glucose required to prepare $$250$$g of $$5\%$$ solution of glucose by mass.



$$4.6 cm^3$$ of methyl alcohol is dissolved in $$25.2$$g of water. Calculate $$\%$$ by mass of methyl alcohol. 
(Given density of methyl alcohol = $$0.7952 gcm^{-3}$$ and $$C = 12, H = 1, O = 16$$)



What is the mass of the precipitate formed when $$50$$mL of $$16.9\%$$ (w/v) solution of $$AgNO_3$$ is mixed with $$50$$mL of $$5.8\%$$ (w/v) $$NaCl$$ solution?
[$$Ag = 107.8, N = 14, O = 16, Na = 23, Cl = 35.5$$]



An atom bomb is weighing 1 kg explodes releasing $$9 \times 10^{13}$$ joule of energy. What percentage of mass is converted into energy?



Calculate the mass percent of different elements in calcium phosphate.



Calculate the percentage composition in terms of mass of a
solution obtained by mixing 300 g of a 25% and 400 g of a 40% solution by mass.



Phosphoric
acid is widely used in carbonated beverages , detergents , toothpastes and
fertilizers . Calculate the mass percentage of H , P AND O in phosphoric acid
if atomis mases are H =1  , P=31 and O = 16



Calculate the mass percentage of different constituent elements in urea.



Rahul Sharma, an intelligent student of class 12 follows the lesson taught in class easily, has friendship with Amit and Krishan who do not follow the lessons easily. Rahul helps Amit and Krishan to understand the concepts and in turn, they are thankful to him. Their friendship is long lasting because both are happy. Rahul feels sense of achievement.
a) Should intelligent students make friends with weak students?Give reason.
b) If you compare this kind of friendship to atoms what kind of bond will be formed.
c) Comment on the strength of such bonding. Name the force that keeps them bonded.
d) Discuss any one property in which these atoms are different from each other.



A solution is prepared by dissolving 5 g urea in 95 g water. What is the mass percent urea in the solution?



In a gaseous mixture 2mol of $${ CO }_{ 2 }$$, 1 mol of $${ H }_{ 2 }$$ and 2 mol of He are present than determine mole percentage of $${ CO }_{ 2 }$$.



At $$-50^0C$$, liquid $$NH_3$$ has ionic product is $$10^{-30}$$. How many amide $$(NH_2^-)$$ ions are present per $$mm^3$$ in pure liquid $$NH_3$$? (take $$N_A = 6 \times 10^{23}$$)



What weight of zinc would be required to produce enough hydrogen to reduce 8.5 g of copper oxide completely into copper?



Calculate the mass of potassium chlorate required to liberate 6.72 of oxygen at STP.
[Assume: molar mass of potassium chlorate as 122.5 g / mol].



Name the purest form of commercial ion.



44.8 L of $$CO_{2}$$ at NTP is obtained by heating $$x$$ g of pure $$CaCO_{3}.x$$ is:



By the reaction of carbon and oxygen, a mixture of $$CO$$ and $$CO_{2}$$ is obtained. What is the composition(% by mass) of the mixture obtained when 20 grams of $$O_{2}$$ reacts with 12 grams of carbon ?



Show that ''Law of conservation of mass is fully justified in a balanced chemical equation''.



A solution of ethanol in water is $$10%$$ by volume. If the solution and pure ethanol have densities of $$0.9866\ g/cc$$ and $$0.785\ g/cc$$ respectively, find the percent by weight.



If the atomic mass of sodium is $$23u$$, what will be the atomic mass of sodium ion?



$$15.9 \,g$$ of copper sulphate and $$10.6 \,g$$ of sodium carbonate react together to give $$14.2 \,g$$ of sodium sulphate and $$12.3\,g$$ of copper carbonate. Which law of chemical combination is obeyed? How?



Calculate the percentage loss of mass of hydrated copper [II] sulphate $$[ Cu{ SO }_{ 4 }]$$ when it is completely dehydrated. 
 [$$Cu{ SO }_{ 4 }\cdot 5{ H }_{ 2 }O\rightarrow Cu{ SO }_{ 4 }+5{ H }_{ 2 }O$$]
[At. wts. are Cu = 64, S = 32, O = 16, H = 1].



 A solution of ethanol in water is $$10%$$ by volume. If the solution and pure ethanol have densities of  $$0.9866 glcc$$ and $$0.785 g/cc$$ respectively, find the percent by weight. 



The mole fraction of benzene in a solution in toluene is $$0.40$$. Calculate the weight per cent of benzene in the solution.



Define the law of conservation of mass.



$$27.6$$ g $${K_2}C{O_3}$$ was treated by a series of reagents so as to convert all of its carbon to $${K_2}Z{n_3}{\left[ {Fe{{\left( {CN} \right)}_6}} \right]_2}$$ The weight of product is?



The percent loss in weight after heating a pure sample of potassium chlorate (mol. wt. = 122.5) will be ($${KCIO  }_{3  }\rightarrow KCI +{  O}_{2  }$$)



Phosphoric acid is widely used in carbonated beverages, detergents, toothpastes and fertilizers. Calculate the mass percentages of $$H. P$$ and $$0$$ in phosphoric acid if atomis mases are $$H = 1, P = 31$$ and $$0 = 16$$. (Ans. $$H - 3.06\%, P - 31.63\%, 0-65.31\%)$$ 



At STP, 2.8 liters of hydrogen sulphide were mixed with 1.6 liters of sulphur dioxide and reaction occurred according to the equation :
$${ 2H }_{ 2 }S(g)+{ SO }_{ 2 }(g)\longrightarrow { 2H }_{ 2 }O(l)+3S(s)$$



Calculate  the molality in the aqueous solution containing $$3.0gm$$ of urea in $$250gm$$ of water 
($$H=1,N=14,O=16$$)



Two samples 'm' and 'n' of slaked lime, $$Ca(OH)_2$$, were obtained from two different reactions. The details about their composition are as follows:

$$\underline {Sample\ 'm'}$$ 
Total mass: 7 g
Mass of constituent oxygen: 2 g
Mass of constituent calcium: 5 g

$$\underline {Sample\ 'n'}$$
Total mass: 1.4 g
Mass of constituent oxygen: 0.4 g
Mass of constituent calcium: 1 g

Which law of chemical combination does this prove? Explain.



Evaporation of water occurs at all temperature 
How is eveporation dependent on temperature ?



Why does water vapour condense when it reaches high up in the atmosphere ?



At what temperature does water boil ?



Determine the percentage composition of each atom in the molecule of $${ Na } _ { 2 }  { CO } _ { 3 }$$.



Name any two laws of chemical combination.



How to calculate the atomic mass?



Chlorine has two isotopes of atomic mass units 34.97 and 36.The relative abundance of an isotope is 0.755 and 0.245 respectively. Find the average atomic mass of chlorine.



The atomic number of an element is more important to the chemist than its relative atomic mass. Why?



The weight of 350 mL of a diatomic gas at $$0^0C$$ and 2 atm pressure is 1 g. The wt. of one atom is 



a) Define atomic mass unit.
b) Distinguish between molecular mass and molar mass.
c) Give an example of (i) diatomic, (ii) triatomic molecule of compounds.



How many grans of concentrated sitric acid $$sol^n$$ should be used to prepare $$250$$ mL of $$2$$ M $$HNO_3$$ ?
The concentrated acid is $$70\%$$ $$HNO_3$$ ?



Calcium chloride, when dissolved in water, dissociates into its ions according to the following equation :
$$ CaCl_{ 2 (aq)} \rightarrow Ca^{2+}_{aq} +2Cl^- _{aq} $$
Calculate the number of ions obtained from $$ CaCl_2 $$ when 222 g of its dissolved in water.



Distinguish between molecular mass and molar mass.



An atom of an element is $$10.1$$ times heavier than the mass of a carbon atom. What is its mass in a.m.u?



A gaseous mixture of $$H_{2}$$ and $$N_{2}O$$ gas contains 66 mass $$\%$$ of $$N_{2}O$$. What is the average molecular mass of mixture?



How many amu's are present in $${10^{ - 3}}$$g?



Express unified atomic mass unit in kg.



1 L of $$CO_2$$ is passed over hot coke.When the volume of reaction mixture becomes 1.4 L, the composition of reaction mixture is 



Chlorine has two stable isotopes: Cl-35 and Cl-37 with atomic masses 34.96 and 36.95, respectively. If the average mass of chlorine is 35.43, calculate the percentage abundance. 



Take 30 g of common salt and dissolve it in 70g of water. Find the concentration of a solution in terms of weight percent.



The saturation temperature for 20.7g of $$CuSO_4$$ soluble in water is_______.



Complete the table given below:
ElementAtomic massMolecular massAtomicity number
Chlorine35.571-
Ozone-483
Sulphur32-8
Nitrogen14-2



To make a saturated solution, 36 g of sodium chloride is dissolved in 100 g of water at 293 K. Find its concentration at this temperature.



Complete the following table:
ElementMass numberAtomic Numbernumber of Electronsnumber of  protonsnumber of neutrons
Phosphorous3115
Potassium1920



What is the active mass of 1L of oxygen gas at N.T.P?



Calculate the formula unit masses of ZnO, $$Na_2O$$, $$K_2CO_3$$, given atomic masses of Zn = 65u, Na= 23 u, K= 39 u, C= 12 u, and O= 16 u,



$$\displaystyle  3.90\, g $$ of a mixture of $$ Al $$ and $$ Al_2O_3 $$, when reacted with a solution of sodium hydroxide, produced $$ 840 \,mL $$ of a gas at NTP. Find the composition of the mixture.



Radium disintegrates at an average rate of $$ 2.24 \times  10^{13} \alpha $$ particles per minute. Each $$ \alpha $$-particle takes up two electrons from the air and becomes a neutral helium atom. After 420 days, helium gas collected was 0.5 mL, measured at $$ 27^0 C $$ and 750 mm Hg. Calculate the Avogadro constant.



How many years would it take to spend the Avogadro constant of rupees at the rate of $$10$$ lakh rupees per second? 



$$3.2\ g$$ of a mixture of $$KNO_{3}$$ and $$NaNO_{3}$$ was heated to constant weight which was found to be $$2.64\ g$$. What is the $$\%$$ of $$KNO_{3}$$ in mixture?



What is the weight of one atom of H in g (at. wt. of H = $$1.008$$)?



A mixture of $$FeO$$ and $$Fe_3O_4$$ when heated in air to constant weight gains $$5$$% in its weight. Find out composition of mixture.



Does $$1$$ g of all elements contain nucleons equal to the Avogadro constant? Explain.



Find the weight of $$H_2SO_4$$ in $$1200\,mL$$ of a solution of $$0.4\,N$$ strength.



Find the weight of $$NaOH$$ in its $$60$$ milli - equivalents.



The rate of diffusion of a sample of ozonised oxygen is $$0.98$$ times more than that of pure oxygen. Find the percentage (by volume) of ozone in the ozonised sample. Also report percentage by weight.



Name the law of chemical combination :
(a) Which was given by Lavoisier 
(b) Which was given by Proust 



A mixture of $$NH_3(g)$$ and $$N_2H_4(g)$$ is placed in sealed container at $$300 K.$$The total pressure is $$0.5 \,atm.$$ The container is heated to $$1200 K,$$ at which time both substances decompose completely according to the equations :
$$2NH_3(g) \rightarrow N_2(g) + 3H_2(g)$$
$$N_2H_4(g) \rightarrow N_2(g) + 2H_2(g)$$
After decomposition is complete, the total pressure at $$1200\,K$$ is found to be $$4.5\,atm.$$ Find the amount (mole) percent of $$N_2H_4(g)$$ in the original mixture?



Fill in the blanks :
In water, the proportion of oxygen and hydrogen is _____ by mass. 



Name the scientist who gave :
(a) Law of conservation of mass 
(b) Law of constant proportions 



Explain giving a suitable example:
Law of conservation of mass.



What is meant by law of conservation of mass? If 12 g of $$C$$ is burnt in the presence of 32 g $$O_2,$$ how much $$CO_2$$ will be formed?



Who is the father of chemistry? Why?



Calculate the average atomic mass of hydrogen using the following data:
Isotope$$\%$$ Natural abundanceMolar mass
$$^1 H$$$$99.985$$$$1$$
$$^2H$$$$0.015$$$$2$$



Calculate the mass of potassium sulphate required to prepare its $$10\%$$ solution in $$100 \,g$$ of water.



Define atomic mass.



Calculate the mass of sodium sulphate required to prepare its $$20\%$$ (mass percent) solution in $$100g$$ of water.



Calculate the mass percent of calcium, phosphorous and oxygen in calcium phosphate $$Ca_3(PO_4)_2$$.



Explain fractional atomic mass. What is the fractional mass of chlorine?



The total number of protons and neutrons in the nucleus of an atom is known as .



State the law of conservation of matter or mass.



Define law of conservation of mass for a chemical reaction.



Explain the need for a reference atom for atomic mass. Give some information about two reference atoms.



If bromine atom is available in isotopes  $$ _{ 79 }^{ 35 }{ H } (49.7$$ %) and $$ _{ 81 }^{ 35 }{ H } $$Br $$(50.3$$ %) Calculate the average atomic mass of bromine atom. 



Give reasons
Actual atomic mass is greater than mass number.



What is meant by unified mass, u?



Name the fundamental law involved in every chemical reaction.



What is Avogadro's law? Explain Boyle's law and Charle's law with graph.



Write a short note on Avogadro's Hypothesis and its applications.



Mention the signification of mole.



State Avogadro's law.



What is meant by the relative atomic mass of an element?



Calculate the relative molecular mass of carbon dioxide.



What is meant by the relative molecular mass of a substance?



Why are the atomic masses of most of the elements fractional?



Briefly explain laws of chemical combinations.



Calculate the percentage composition of carbon and oxygen in $$CO_2$$.

(Given atomic masses: Carbon $$= 12$$ and Oxygen$$= 16$$).



What do you understand from the statement that the atomic mass of Helium is $$4$$?



One GAM substance contains Avogadro number of particles in it.
How many particles are there in Avogadro number?



One GAM substance contains Avogadro number of particles in it.
Write the number of atoms present in each of the following.
$$32g$$  Oxygen
(Atomic mass $$S=32, O=16, C=12$$)



One GAM substance contains Avogadro number of particles in it.
Write the number of atoms present in each of the following.
$$32g$$ Sulphur
(Atomic mass $$S=32, O=16, C=12$$)



Is their any relation between the mass of the number, if the particles are of the same mass.



One GAM substance contains Avogadro number of particles in it.
Write the number of atoms present in each of the following.
$$32g$$  Carbon
(Atomic mass $$S=32, O=16, C=12$$)



Find out the mass of one mole of $$CaCo3$$. How many moles of calcium present in $$1000\ g\ \ CaCo3$$?



What may be the method of stating the mass of atoms?



According to Avagadro's law when the temperature and pressure remain constant on which factor does the volume of gas depend?



Why are atomic mass of some elements are in fractions ?



Calculate percentage elements present in ammonium chloride $$(NH_4Cl)$$
$$(N=14, H=1, Cl=35.5)$$



What is meant by atomic mass and molecular mass?



Explain the combination capacity of an atom.



Complete the flow chart given below, related to one mole of substance.
1834449_97d9815ad0ff4437a093a54c8419d166.png



A gas mixture of $$ 3 \cdot 0 $$ litres of propane and butane on complete combustion at $$ 25^{0}C $$ produced 10 litres of $$ CO_{2}. $$ Find out the composition of the gas mixture.                                      $$ \textbf (M.L.N.R. Allahabad\;1992) $$



What is kg-mole? Find out the total number of electrons in a kg-mole of $$ O_{2}. $$



$$ 20 \cdot 0 mL $$ of a mixture of oxygen $$ (O_{2}) $$ and ozone $$ (O_{3}) $$ was heated till ozone was completely decomposed. The mixture on cooling was fond to expand to $$ 21 mL $$. Calculate the percentage of ozone by volume in the mixture.



Why atomic mass is an average value? Explain with a suitable example.



Why Law of conservation of mass should better be called as Law of conservation of mass and energy?



Define atomic mass, and give suitable examples.



Briefly explain the importance of studying chemistry.



Naturally occurring Boron consists of two isotopes whose atomic weights are $$ 10 \cdot 01 $$ and $$ 11 \cdot$$ The atomic weight of natural Boron is $$ 10 \cdot$$ Calculate the percentage of each isotope in natural Boron.                                     $$ \textbf{(M.L.N.R.Allahabad 1994)} $$



The law which states that a chemical compound always contains the same elements combined in a fixed ratio by mass is called _________.



Calcium nitrate decomposed on heating according to the equation:
$$2Ca(NO_{3})_{2} \rightarrow 2CaO + 4NO_{2} + O_{2}$$
The molecular mass of calcium nitrate is 164 u.
Calculate:
a. the volume of nitrogen dioxide $$(NO_{2})$$ obtained at S.T.P.
b. the weight of calcium oxide obtained when 16.4 g of calcium nitrate is heated to constant weight. [Ca = 40, 0 = 16, N = 14]



When $$400$$ g of a $$20$$% solution by weight was cooled, $$60$$ g of solute is precipitated. The percentage concentration of the remaining solution is $$x \%$$. 
The value of $$x$$ is _______.
(Round figure the answer up to nearest integer value)



The percentage of copper in a copper(II) salt can be determined by using a thiosulphate titration. 0.305 gm of a copper(II) salt was dissolved in water and added to an excess of potassium iodide solution liberating iodine according to the following equation.
$$2Cu^{2+} (aq) + 4I^- (aq)\rightleftharpoons  2CuI(s) + I_2(aq)$$
The iodine liberated required $$24.5 \:cm^3$$ of a $$0.100 \:mole \:dm^{-3}$$ solution of sodium thiosulphate
          $$2S_2{O_{3}}^{{2-}}(aq) + I_2 (aq)\rightarrow   2I^-(aq) + S_4{O_{6}}^{{2-}}(aq)
$$
the percentage of copper, by mass in the copper(II) salt is: $$[Atomic \: mass \: of \: copper = 63.5]$$



One type of artifical diamond (commonly called $$YAG$$ for yttrium aluminium garnet) can be represented by the formula $$Y_{3}Al_{5}O_{12}$$ [$$Y=89, Al=27$$]. Match element present in List-I with their weight percentages given in List-II.



A sample of clay was partially dried. It was then found to contain $$50\%$$ silica and $$7\%$$ water. The original clay contained $$12\%$$ water. Find the percentage of silica in the original sample (as nearest integer).



A mixture of $$CuSO_4$$ and $$CuSO_4 \, .5H_2O$$ has a mass of $$1.245$$ g. After heating, it drives off all the water, the mass is only $$0.832$$ g. What is the mass (in mg) of $$CuSO_4.5H_2O$$ in the mixture?



The percentage (by mass) concentration of a solution obtained by mixing $$300$$ g of a $$25$$% (solution $$I$$) and $$400$$ g of a $$40$$% (solution $$II$$) by mass is (as the nearest integer):



A solution of a specific gravity $$1.6\ g\ {mL}^{-1}$$ is $$67\%$$ by mass. The $$\%$$ by mass of the solution of the same acid, if it is diluted to the specific gravity $$1.2\ g\ {mL}^{-1}$$ is (as nearest integer) :



A regular co-polymer of ethylene and vinyl chloride contains alternative monomers of each type. The mass percent of ethylene in this co-polymer is (as the nearest integer) :



Cytochrome c is an iron-containing enzyme found in the cells of all aerobic organisms. If cytochrome c is $$0.43\%$$ $$Fe$$ (atomic mass = 56 amu) by weight, then the minimum molecular weight (Kg.mol$$^{-1}$$) is $$6.5X$$. Then $$X$$ is:



A polystyrene having the formula $${Br}_{3}{C}_{6}{H}_{3}{({C}_{8}{H}_{8})}_{n}$$, was prepared by heating styrene with tribromobenzoyl peroxide in the absence of air. 

If it was found to contain $$10.46\%$$ of bromine by mass, the value of $$n$$ is:



When $$400$$ g of a $$20\%$$ solution by mass was cooled, $$50$$ g of solute precipitated. The percentage (by mass) concentration of the remaining solution is (as the nearest integer) :



To prepare $$100$$ g of a $$92$$% by weight solution of $$NaOH$$, how many grams of $$H_2O$$ is needed?



One mole of an ideal gas at standard temperature and pressure occupies 22.4 L(molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen ? (Take the size of hydrogen molecule to be about 1). 
Why is this ratio so large ?



1 litre of $$N_2$$ and $$\cfrac{7}{8}$$ litre of $$O_2$$ at same temperature and pressure were mixed together. The ratio of the masses of two gases in the mixture is _______.



A $$0.24\ g$$ sample of compound of oxygen and boron was found by analysis to contain $$0.096\ g$$ of boron and $$0.144\ g$$ of oxygen. Calculate the percentage composition of the compound by weight.



The relative atomic mass of an element A is $$16.2$$ there are two isotopes $$_{8}^{16}A$$ and $$_8^{18}A$$ of the element. Calculate the percentage of these two isotopes present in the element.



In an experiment $$1.288\ g$$ of copper oxide was obtained from $$1.03\ g$$ of copper and $$0.258\ g$$ of oxygen. Calculate the ratio of copper and oxygen in the sample?



In a Gobar gas plant, gobar gas is formed by bacterial fermentation of animal refuse. It mainly contains methane and its heat of combustion is $$-809\ kJ$$ $${mol}^{-1}$$ according to the following equation:
$${ CH }_{ 4 }+2{ O }_{ 2 }\longrightarrow { CO }_{ 2 }+2{ H }_{ 2 }O;\Delta H=-809\ kJ\quad $$
How much gobar gas would have to be produced per day for a small village of $$50$$ families, if it is assumed that each family requires $$20,000\ kJ$$ of energy per day? The methane content in gobar gas is $$80$$% by mass.



$$One\ gram$$ of charcoal adsorbs $$100\ mL$$ of $$0.5\ M\, CH_3COOH$$ to form a monolayer and thereby the molarity of acetic acid is reduced to $$0.49\ M$$. Calculate the surface area of the charcoal adsorbed by each molecule of acetic acid. Surface area of charcoal $$= 3.01 \times 10^2\, m^2/gm$$. 



A commercial sample (2.013 g) of NaOH containing $$Na_2CO_3$$ as an impurity was dissolved to give 250 mL of solution. A 10 mL portion of the solution required 20 mL of 0.1 N $$H_2SO_4$$ solution for complete neutralisation of $$NaOH$$. Calculate the percentage by weight of $$Na_2CO_3$$ in the sample.[Write up to 2 decimal places]



A gas cylinder can hold 1 Kg of hydrogen at mom temperature and pressure:
i) Find the number of moles of hydrogen present
ii) What weight of $$CO_{2}$$ can the cylinder hold under similar conditions of temperature and pressure? ($$H=1,\ C=12,\ O=16$$)
iii) If the number of molecules of hydrogen in the cylinder is $$X$$, calculate the number of $$CO_{2}$$ molecules in the cylinder under the same conditions of temperature and pressure
iv) State the law that helped you to arrive at the above result. 



$$10g$$ of a sample of $$Ba(OH)_2$$ is dissolved in $$10mL$$ of $$0.5N$$ $$HCl$$ solution. The excess of HCl was titrated with $$0.2N$$ $$NaOH$$. The volume of $$NaOH$$ used was $$20cc$$. Calculate the percentage of $$Ba(OH)_2$$ in the sample.



Calculate the mass percentage of benzene $$\left( {C_6 H_6 } \right)$$ and carbon tetrachloride $$\left({CCl_4}\right)$$ if $$22\ g$$ of benzene is dissolved in $$122\ g$$ of carbon tetrachloride.



How many g of a $$5.0\%$$ by weight NaCl solution are necessary to yield $$3.2$$g NaCl?



How many $$Cl$$ atoms can you ionize in the process $$Cl\rightarrow {Cl}^{+}+e$$ by the energy liberated for the process $$Cl+e\rightarrow {Cl}^{-}$$ for one Avogadro number of atms. Given $$IP=13.0eV$$ and $$EA=3.60eV$$. Avogadro number $$=6\times {10}^{23}$$.



An element has average atomic mass $$20.426u$$ it has $$2$$ isotopes with masses $$22.1824$$ and $$19.9574$$. Calculate the abundance of its isotopes $$X-22$$ and $$X-20$$.



$$0.2g$$ of an organic compound on analysis given $$0.147g$$ of carbondioxide, $$0.12g$$ of water and $$74.6 c.c$$ of nitrogen at STP. Calculate the weight percentages of constituents. 



A solution contains 40 g of common salt in 320 g of water. Calculate the concentration in terms of mass by mass percentage of the solution.



Which would be larger : an atomic mass unit based on the current standard or one based on the mass of a Be- 9 atom set at exactly 9 amu ?



Density of dry air (only $$N_{2}$$ & $$O_{2}$$) is $$1.146\ g\ litre^{-1}$$ at $$740\ mm$$ and $$300 K$$.  Calculate composition of air by weight assuming ideal nature. 



Compute the number of ions present in $$5.85$$ g of sodium chloride.



A sample of lead weighing $$1.05g$$ was dissolved in a small quantity of nitric acid to produce an aqueous solution of $${Pb}^{2+}$$ and $${Ag}^{+}$$ (which is present as impurity). The volume of the solution was increased to $$300ml$$ by adding water, a pure silver electrode was immersed in the solution and the potential difference between this electrode and a standard hydrogen electrode was found to be $$0.503V$$ at $${25}^{o}C$$. What was the % of $$Ag$$ in the lead metal? (Given : $${ E }_{ ({ Ag }^{ + }/Ag) }^{ o }=0.799V$$. Neglect amount of $${Ag}^{+}$$ converted to $$Ag$$)



Average atomic weight of an element $$M$$ is $$51.7$$. If two isotopes of $$M,\ M^{50}$$ and $$M^{52}$$ are present, then calculate the percentage of occurrence of $$M^{50}$$ in nature.



The balanced equation for a reaction is given below 
           $$2X + 3Y \to {\text{4I + m}}$$
When 8 moles of x react with 15 moles of y, then 
i) Which is the limiting reagent?
ii) Calculate the amount of products formed.
iii) Calculate the amount of excess reactant left at the end of the reaction.



Samples of $$O_2, N_2$$ and $$CO_2$$ under the same conditions of temperature & pressure contain the same number of molecules represented by $$X$$. The molecules of oxygen occupy $$V$$ litres and have a mass of $$8\ g$$. Under the same conditions of temp and press., what is the volume occupied by: 
i) $$X$$ molecule of $$N_2$$
ii) $$3X$$ molecules of $$CO_2$$
iii) What is the mass of $$CO_2$$ in grams.
iv) In answering the above questions, whose law has been used.



A mixture of CO of $$CO_2$$ is found to have a density of $$1.5gm/ L$$ at $$30^oC$$ & 730 torr What is the composition of the mixture.



One of the methods of preparation of per disulphuric acid, $$ H_2S_2O_8 $$ involve electrolytic oxidation of $$ H_2SO_4 $$ at anode $$ (2H_2SO_4 \rightarrow H_2S_2O_8 +2H^+ +2e^-) $$ 
with oxygen and hydrogen as by-products. In such an electrolysis, 9.722 L of $$ H_2 $$ and 2.35 L of $$ O_2 $$ were generated at STP. What is the weight of $$ H_2S_2O_8 $$ formed ?



In a aqueous solution of urea, the mole fration of urea is $$0.2$$. Calculate the mass $$\%$$ of solute



A mixture of $$FeO$$ and $$Fe_{3}O_{4}$$ when heated in air to a constant weight gains $$5\%$$ in its weight. Find the composition of initial mixture.



A mixture containing $$NaHCO_{3}$$ and $$Na_{2}CO_{3}$$ weighed $$1.0235\ g$$. The dissolved mixture was reacted with excess of $$Ba(OH)_{2}$$ to form $$2.1028\ g\ BaCO_{3}$$ by the reactions;

$$Na_{2}CO_{3}+Ba(OH)_{2}\rightarrow BaCO_{3}+2NaOH$$

$$NaHCO_{3}+Ba(OH)_{2}\rightarrow BaCO_{3}+NaOH+H_{2}O$$

What is the percentage of $$NaHCO_{3}$$ in the mixture?$$[Ba=137]$$



A $$2.0\ g$$ of sample containing $$Na_{2}CO_{3}$$ and $$NaHCO_{3}$$ loses $$0.248\ g$$ when heated to $$300^{o}C$$. What is the percentage of $$Na_{2}CO_{3}$$ in the mixture. 

Write your answer to the nearest integer.



A precipitate of $$AgCl$$ and $$AgBr$$ weighs $$0.4066\,g.$$ On heating in a current of chlorine, the $$AgBr$$ is converted to $$AgCl$$ and the mixture loses $$0.0725\,g$$ in weight. Find the $$\%$$ of $$Cl$$ in origijnal mixture.



The total pressure of a mixture of $$H_2$$ and $$O_2$$ is $$1.0$$ bar. The mixture is allowed to react to form water, which is completely removed to leave only pure $$H_2$$ at a pressure of $$0.35$$ bar. Assuming ideal gas behaviour, and that all pressure measurements were made under the same temperature and volume conditions, calculate the composition of the original mixture.



A $$5.0\,g$$ sample of a natural gas consisting of $$CH_4, C_2H_4$$ was burnt in excess of oxygen yielding $$14.5\,g\,CO_2$$ and some $$H_2O$$ as product. What is weight percentage of $$CH_4$$ and $$C_2H_4$$ in mixture.



If the value of Avogadro number is $$ 6.023 \times  10^{23} mol^{-1} $$ and the value of Boltzmann constant is $$  1.380 \times  10^{-23} JK^{-1} $$, then the number of significant digits in the calculated value of the universal gas constant is: 



A mixture containing $$2.24$$ litres of $$H_2$$ and $$1.12$$ litres of $$D_2$$ at NTP is taken inside a bulb connected to another bulb by a stopcock with a small opening. The second bulb is fully evacuated, the stopcock opened for a certain time and then closed. The first bulb is now found to contain $$0.10\ g\ H_2$$. Determine the percentage composition by weight of the gases in the second bulb.



Fill in the following blank with a suitable word.
Chemical equations are balanced to satisfy the law of ___________.
Enter 1 for 'conservation of mass' or 2 for 'chemical combination'.



A sample of Mg metal containing some MgO as impurity was dissolved in $$125\,mL$$ of $$0.1\,N\,H_2SO_4.$$ The volume of $$H_2$$ evolved at $$27.5^\circ C$$ and 1 atm was $$120.0\,mL.$$ The resulting solution was found to be $$0.02N$$ with respect to $$H_2SO_4.$$ Calculate the weight of sample dissolved and the $$\%$$ by weight of pure Mg metal in sample. Neglect any charge in volume by weight of pure Mg metal in sample. Neglect any change in volume.



A plant virus is found to consist of uniform cylindrical particles of $$150\overset{o}{A}$$ in diameter and $$5000\overset{o}{A}$$ long. The specific volume of the virus is $$0.75$$ $$cm^3/g$$. If the virus is considered to be a single particle, find its molecular weight.



Use the following data to calculate Avagodro's number(N). Density of NaCl=2.165 g $$cm^{-3}$$. Distance between $$Na^{+}$$ and $$Cl^{-}$$ in NaCl=281 pm.

[If $$ x \times 10^{23} $$ is the answer then find the value of $$x$$ to the nearest integer]



A gas mixture of 3 litre of propane and butane on complete combustion at $$25^\circ C$$ produced 10 litre of $$CO_2.$$ Find out the composition of mixture.



How much is 1 a.m.u?



Fill in the blanks :
The quantity of matter in an object is called its ______.



Fill in the blanks 
In a chemical reaction , the sum of the masses of the reactants and the products remains unchanged . This is called _____ . 



Fifty millilitre of a mixture of $$CO$$ and $$CH_{4}$$, was exploded with $$85 ml$$ of $$O_{2}$$. The volume of $$CO_{2}$$, produced was $$50 ml$$, Calculate the percentage composition of the gaseous mixture.




Why atomic masses are the average values?



Class 11 Medical Chemistry Extra Questions